Alkanes
Alkanes are hydrocarbons with single bonds between 2 consecutive C atoms
Physical Properties of Alkanes
Examples:
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2,2 dimethylbutane: boiling point = 49oC.
Structure of the –C-C– bond
- The C- C bond each carbon atom is sp3 hybridized with 109o bond angles and tetrahedral structure.
- These orbitals then form a sigma (σ) bond with each hydrogen or carbon. These bonds can rotate.
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- Most alkanes can exist as a unique chain (linear), branched, or forming rings (cycloalkanes) Note that cycloalkanes do not have the same general formula of alkanes.

Chemical properties
The C-C and C-H bonds in alkanes are very strong since they are non-polar covalent compounds, therefore, alkanes are relatively inert in regards to most chemical reagents.They can react under certain conditions in the following reactions:-
- Combustion (Oxidation – Burning)
- Catalytic or thermal cracking, also called PYROLYSIS (Breaking the molecule in smaller parts using catalysts or heat).
- Substitution reactions (One or more of the hydrogen atoms in the molecule is replaced
A) Combustion
1) Complete combustion
Alkanes burn in with enough amount of oxygen to produce CO2 and H2O.
Gases burn much more easily than liquid and solid alkanes. A gaseous mixture of a small alkane and oxygen are extremely explosive.
2C2H6(g) + 7O2(g) → 4CO2(g) + 6H2O(g)
These reactions are used commercially when fuels such as natural gas, petrol and oil are burnt in air.
2) Incomplete combustion
Incomplete combustion (where there isn’t enough oxygen present) can lead to the formation of carbon and/or carbon monoxide. Carbon monoxide is produced as a colorless poisonous gas.
2CH4(g) + 2O2 (g) → 2CO (g) +4H2O (g)
Carbon monoxide form an irreversible compound with hemoglobin – making it unable to carry oxygen. If you breath in enough carbon monoxide you will die not because you cannot breath but because the oxygen cannot be transported inside your blood.
B) Catalytic or thermal cracking
Big molecules of Alkanes are heavy, they do not flow or burn easy. Our industry needs smaller and more reactive materials. We can use themal cracking to break these large molecules into smaller ones. The sample is vaporized and passed over a hot catalyst. Bonds inside the molecule are broken and double bonds are formed since there is a lack of hydrogens saturate the new compounds. It is a random process so the double bonds can produce a mixture of compounds. Since one molecule is broken in two, cracking is an example of a thermal decomposition reaction.
The reaction above shows the cracking reaction of an alkane (Octane) to obtain hexane and ethene (notice the double bond in ethene)
The animation below shows the reaction in an interactive way.
source: http://www.bbc.co.uk/schools/gcsebitesize/science/aqa_pre_2011/oils/polymersrev1.shtml The following video shows the cracking of alkanes and how to recognize the alkenes obtained source: http://www.youtube.com/watch?v=ZYyKUePdC2YThese reactions are used commercially when fuels such as natural gas, petrol and oil are burnt in air.
C) Substitution reactions (Chlorine or Bromine)These reactions of alkanes with all halogens are very similar, the rate of reaction is the only difference. We will concentrate in one example but remember that once you know one of them, you know them all.
A mixture of chlorine and methane:
a) Does not react if kept in the dark at room temp.
b) Does not react if kept in the dark at 300oC
c) Reacts at room temperature if exposed to sunlight or U.V. light.
d) Explodes if exposed to bright sunlight or sparked.

These products are explained in terms of a step by step reaction:
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- CH4(g) + Cl2(g)
CH3Cl(g) + HCl(g)
- CH3Cl(g) + Cl2(g)
CH2Cl2(g) + HCl(g)
- CH2Cl2(g) + Cl2(g)
CHCl3(g) + HCl(g)
- CHCl3(g) + Cl2(g)
CCl4(g) + HCl(g)
- CH4(g) + Cl2(g)
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Each of these reaction is an example of a substitution reaction (a H atom is substituted by a Cl atom)
Mechanism: FREE RADICAL SUBSTITUTION
power point presentation about MECHANISMS

- Initiation: the free radical form
- Propagation: the free radical reacts with more molecules forming more free radicals
- Termination: two free radicals get together forming new molecules


