Define polymers as… ● Large molecules built up from small units (monomers) Understand that different polymers have different units and/or different linkages ● Each polymer is made from a certain monomer or monomers, therefore different polymers have different units and/or different linkages (depending on how the monomer(s) join up to form the polymer) ● monomers can be different lengths or can have different groups attached ● can have a C-C linkage, ester linkage or amide linkage
Polymerisation
Polymer
A large molecule produced when small molecules join together. These small molecules are called monomers.
There are two types of polymers: natural and synthetic
Natural Polymers:
The ones we find in nature: cellulose, starch, proteins nails, hair, bones, muscles, etc.
Synthetic Polymers:
The ones that are man-made. Nylon, polystyrene (Styrofoam), polyesters, polyamides, PVC etc.
It is the process of producing a polymer. There are two types of polymerisation
AdditionPolymerisation:
All the atoms in the monomer are used to form the polymer
Example:
Many molecules of Ethene ==> Polyethene
Condensation Polymerisation:
All monomers join up forming a small molecules that are released in the process. Most of the time the molecule is water or a hydrogen halide. (Hydrogen chloride for example)
Many molecules of Aminoacid ===> protein + water
Addition Polymers
Facts:
during polymerisation, an alkene undergoes an addition reaction with itself.
All the atoms in the original alkenes are used to form the polymer
Long hydrocarbon chains are formed
The equation shows the original monomer and the repeating unit in the polymer
Condensation Polymers
Before speaking about condensation polymerization, you should recognize the main functional organic groups used in polymerization
These functional groups can be in both sides of the molecule or combined, as follows:
Note: the green boxes between the functional groups are generic branches. We do not concentrate in this. We only look at the reaction within the functional groups and how the polymerizationtakes place.
In the condensation Polimerisation, different monomers get together and one of the following molecules will be produced (H2O or HCl)
We will study only 4 types of condensation polymers:
Proteins or polypeptides
Starch or Polysaccharides
Terylene or Polyesters
Nylon or Polyamides
The monomers for the condensation polymers we will study are as follows:
Proteins
When 2 aminoacids combine, they form a dipeptide.
If three aminoacids combine, we have a tripeptide.
With more than 30 aminoacids, we have a special polypeptides. We call them proteins.
chains can be lined up with each other
the C=O and N-H bonds are polar due to a difference in electronegativity
hydrogen bonding exists between chains. Many are soluble in water.
water is formed between the OH of the acid and the H of the amino group. (that is why we call them condensation polymers)
Starch
Starch is made of many diol molecules that get together to form a polymer.
In the process they release water.
That is why this is called CONDENSATION POLYMERIZATION.
Below you have many diol molecules.
By losing water they will become what we call STARCH
Glucose monomers form starch in nature.
Polyesters
Polyesters are formed when dioic acids and diols combine to form ester groups.